Issue 3, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Unusual alkylidene-bridged complexes of nickel by α-H abstraction from a nickelacycle. Crystal and molecular structure of [{Ni2(CHCMe2-o-C6H4)Cl(PMe3)2}2]

Ernesto Carmona,   Enrique Gutiérrez-Puebla,   Angeles Monge,   Margarita Paneque  and  Manuel L. Poveda  

Abstract

The pseudoallylic complex [Ni(η3-CH2C6H4-o-Me)Cl(PMe3)] effects α-H abstraction from the metallacycle [[graphic omitted]H4)(PMe3)2] under very mild conditions, with formation of an alkylidene-bridged tetrametallic species of composition [{[graphic omitted]H4)Cl(PMe3)2}2].

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Article information

DOI
https://doi.org/10.1039/C39910000148
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 148-150

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Unusual alkylidene-bridged complexes of nickel by α-H abstraction from a nickelacycle. Crystal and molecular structure of [{Ni2(CHCMe2-o-C6H4)Cl(PMe3)2}2]

E. Carmona, E. Gutiérrez-Puebla, A. Monge, M. Paneque and M. L. Poveda, J. Chem. Soc., Chem. Commun., 1991, 148 DOI: 10.1039/C39910000148

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