The ‘C5Me5Ru’ moiety coordinates at the A ring of estradiol to give both the α and β isomers of the ketonic form [Ru(C5Me5)(η5-estradienonyl)](1a and 1b respectively) and the α isomer of the phenolic form [Ru(C5Me5)(η6-estradiol)][PF6]2a; 1a reacts with HPF6 to give quantitatively 2a, but in the presence of NEt31a was regenerated.
D. Vichard, M. Gruselle, H. E. Amouri and G. Jaouen, J. Chem. Soc., Chem. Commun., 1991, 46 DOI: 10.1039/C39910000046
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