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Issue 10, 1991
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Copper complexes of 1,1-di(2-pyridyl)ethyl methyl ether: X-ray crystal structures and reactions with dioxygen

Abstract

The mixed-valence complexes [CuIIL13][CuI2I4](L1= di-2-pyridyl ketone), [CuII(HL2)2][CuI2I4][HL2= 1,1-di(2-pyridyl)ethanol] and [CuIIL32][CuI2I4][L3= 1,1-di(2-pyridyl)ethyl methyl ether] have been isolated from the reactions of CuI with the respective ligands. On interactions with dioxygen the last two complexes are oxidised to [CuII2L22I2] and [CuII2L32(OH)2][CuII3] respectively. The X-ray crystal structures of [CuIIL32][CuI2I4] and [CuII2L32(OH)2][CuII3] are reported.

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Article information


J. Chem. Soc., Dalton Trans., 1991, 2539-2543
Article type
Paper

Copper complexes of 1,1-di(2-pyridyl)ethyl methyl ether: X-ray crystal structures and reactions with dioxygen

S. Bhaduri, N. Y. Sapre and P. G. Jones, J. Chem. Soc., Dalton Trans., 1991, 2539
DOI: 10.1039/DT9910002539

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