SCHEDULED MAINTENANCE
Alkan-2-ones (RCH2COCH3) are obtained by C–C–C–C coupling of the four ligands in the dirhodium complexes, [(C5Me5Rh)2(µ-CH2)2(R)(CO)]+(R = CH3, 13CH3, CD3, C2H5); the reaction is intramolecular.
G. J. Sunley, I. M. Saez, D. J. Gulliver, P. S. Williams and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1991, 193 DOI: 10.1039/C39910000193
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