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Issue 5, 1991
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Synthetic approaches to the alkaloids of the ancistrocladaceae: control of the diastereoisomer excess in the synthesis of axially chiral biaryls: a synthesis of (–)-ancistrocladinine

Abstract

An attempt is made to delineate the factors which control the diastereoisomeric excess in the reactions of 2,6-disubstituted phenyl Grignard reagents with the naphthyloxazoline 2; advantage is taken of the results in a synthesis of the Ancistrocladus alkaloid (–)-ancistrocladinine 19.

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Article information


J. Chem. Soc., Chem. Commun., 1991, 278-280
Article type
Paper

Synthetic approaches to the alkaloids of the ancistrocladaceae: control of the diastereoisomer excess in the synthesis of axially chiral biaryls: a synthesis of (–)-ancistrocladinine

M. A. Rizzacasa and M. V. Sargent, J. Chem. Soc., Chem. Commun., 1991, 278
DOI: 10.1039/C39910000278

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