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Issue 5, 1991
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Vanadium(IV) and mixed-valence vanadium(IV/V) oxygen clusters with novel electronic properties, including the examples [V12As8O40(HCO2)]n(n= 3 or 5)

Abstract

The mixed valence compounds [NHEt3]2[NH2Me2][V12As8O40(HCO2)]·2H2O 1 and Na5[V12As8O40(HCO2)]·18H2O 2 containing isostructural V–O clusters with encapsulated formate ions and different electron populations, and their characterization are reported; in structurally related V–O clusters spin–spin coupling increases with increasing numbers of VIV centres in a nearly continuous way.

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Article type: Paper
DOI: 10.1039/C39910000273
J. Chem. Soc., Chem. Commun., 1991, 273-274

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    Vanadium(IV) and mixed-valence vanadium(IV/V) oxygen clusters with novel electronic properties, including the examples [V12As8O40(HCO2)]n(n= 3 or 5)

    A. Müller, J. Döring and H. Bögge, J. Chem. Soc., Chem. Commun., 1991, 273
    DOI: 10.1039/C39910000273

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