Deprotonated pyruvates and hydroxyacetates, upon collisional activation, undergo loss of CO by anionic rearrangement through alkoxycarbonyl ion complexes, e.g. [graphic omitted] and [graphic omitted] Such processes have been substantiated by labelling (2H, 13C), and production studies.
P. C. H. Eichinger, R. N. Hayes and J. H. Bowie, J. Chem. Soc., Perkin Trans. 2, 1990, 1815 DOI: 10.1039/P29900001815
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