(R)- and (S)-1-Chloro-3-tosyloxypropan-2-ol have been prepared by biocatalysed enantioselective esterification in hexane, and in turn could be readily converted into optically active (chloromethyl)oxirane in high yield.
C. Chen, Y. Liu and M. Marsella, J. Chem. Soc., Perkin Trans. 1, 1990, 2559 DOI: 10.1039/P19900002559
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