At 500 MPa, 1 mol. equiv. of carbon disulphide condenses with 3 mol. equiv. of dialkylcyanamide to afford 2,6-bis(dialkylamino)-4-dialkylthiocarbamoylimino-1,3,5-thiadiazine, the structure of which was determined by X-ray crystallography.
T. Tsuchiya, M. Yasumoto, I. Shibuya and M. Goto, J. Chem. Soc., Perkin Trans. 1, 1990, 1218 DOI: 10.1039/P19900001218
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