Issue 4, 1990

Synthetic ionophores. Part 4. Phase transfer-catalysed synthesis of pyridine-containing macrocycles and their ionophore character

Abstract

Phase transfer-catalysed reactions of pyridine-2,6-dicarboxylic acid dichloride and 2,6-dichloropyridine with oligo(ethylene glycols) provide macrocycles in yields higher than those reported by high dilution or transesterification methods. Extraction and transport studies of some of these macrocycles towards picrates of Li+ Na+, K+, Tl+, Mg2+, Ca2+, and Ba2+ by using chloroform as the nonpolar layer showed that two examples, the pyridino crown ethers (3a) and (5b), transport barium and thallium picrates respectively with significant selectivity.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1990, 965-968

Synthetic ionophores. Part 4. Phase transfer-catalysed synthesis of pyridine-containing macrocycles and their ionophore character

H. Singh, S. Kumar, A. Jain and P. Singh, J. Chem. Soc., Perkin Trans. 1, 1990, 965 DOI: 10.1039/P19900000965

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