The reaction of epoxysilanes with lithiated allylsilanes gives predominantly α-silyl-substituted alcohols(3) which are convenient precursors for the preparation of 1-silyl-substituted 1,4-dienes.
E. Schaumann and A. Kirschning, J. Chem. Soc., Perkin Trans. 1, 1990, 419 DOI: 10.1039/P19900000419
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