The ready available benzonickelacyclopentene complex (Me3P)2[graphic omitted]6H4)(1) has been used to prepare a series of seven-membered ring thione analogues of acid anhydrides and other related derivatives through regioselective sequential insertion reactions of selected unsaturated molecules (CS2, COS, SCNPh, CO, CNBut) into the Ni–C bonds.
J. Cámpora, E. Carmona, P. Palma and M. L. Poveda, J. Chem. Soc., Perkin Trans. 1, 1990, 180 DOI: 10.1039/P19900000180
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