One-electron redox equilibria can be established between electron-affinic compounds (EA) intercalated into DNA and cationic viologens such as benzylviologen. The conditions under which the one-electron reduction potential of EA intercalated into DNA can be determined are described and validated.
R. F. Anderson and K. B. Patel, J. Chem. Soc., Faraday Trans., 1990, 86, 3971 DOI: 10.1039/FT9908603971
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