SCHEDULED MAINTENANCE
A study is made of the kinetic salt effects upon intramolecular electron transfer. These effects are analysed in terms of the solvent and ionic-cloud reorganizations and the influence of the electrolyte on the thermodynamics of the process. The latter seems to be the main cause of the negative effect (decrease in reaction rate) observed in the presence of a supporting electrolyte.
M. Galán, M. Domínguez, R. Andreu, M. L. Moyá, F. Sánchez and J. Burgess, J. Chem. Soc., Faraday Trans., 1990, 86, 937 DOI: 10.1039/FT9908600937
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