Reaction of N(SCl)2+ salts with tin(II) chloride: a new preparative route to salts of the SNS+ cation
Abstract
The salts SNS+X–(X = AlCl4, or SbCl6) have been isolated (> 70% yield) from N(SCl)2+X– by reduction with anhydrous tin(II) chloride in liquid SO2 or CH2Cl2.