Issue 3, 1990
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reactivity of tricyclopentadienyl uranium tetrahydroaluminate

Franco Ossola,   Nicola Brianese,   Marina Porchia,   Gilberto Rossetto  and  Pierino Zanella  

Abstract

The reactivity of [U(cp)3(AlH4)](1)(cp =η5-C5H5) has been studied. With (CH3)3CNC it gives [U(cp)3{CH[double bond, length half m-dash]NC(CH3)3}], with pyridine [U(cp)3(NC5H6)], with CH3CN [U(cp)3(N[double bond, length half m-dash]CHCH3)] and [U(cp)3(NHCH2CH3)], with (CH3)3CNCO, which probably inserts into the U–H bond, [U(cp)3{NC(CH3)3CHO}]. All these new complexes have been characterized by standard spectroscopic methods. In addition compound (1) reacts with ROH, acetaldehyde, and acetone to give the respective [U(cp)3(OR)], with BH3·S(CH3)2 giving [U(cp)3(BH4)], and with CH3l giving [U(cp)3l].

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Article information

DOI
https://doi.org/10.1039/DT9900000877
Article type
Paper

J. Chem. Soc., Dalton Trans., 1990, 877-880

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Reactivity of tricyclopentadienyl uranium tetrahydroaluminate

F. Ossola, N. Brianese, M. Porchia, G. Rossetto and P. Zanella, J. Chem. Soc., Dalton Trans., 1990, 877 DOI: 10.1039/DT9900000877

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