Issue 22, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Terminal arsenido palladium(II) and platinum(II) complexes. X-Ray crystal structure of [{N(CH2CH2PPh2)3}PtAsPh2]BPh4

Franco Cecconi,   Carlo A. Ghilardi,   Stefano Midollini,   Simonetta Moneti,   Annabella Orlandini  and  Giancarlo Scapacci  

Abstract

The Pd0 three-coordinate (np3)Pd, [np3= N(CH2CH2PPh2)3], and the Pt0 pseudotetrahedral (np3)Pt(PPh3) complexes react with R2AsX (R = Me, X = I; R = Ph, X = Cl) and NaBPh4 to give [(np3)MAsR2]BPh4, the first examples of terminal arsenides of platinum metals; the molecular structure of {[N(CH2CH2PPh2)3]PtAsPh2}BPh4 has been established by single-crystal diffraction methods.

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Article information

DOI
https://doi.org/10.1039/C39900001583
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1583-1584

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Terminal arsenido palladium(II) and platinum(II) complexes. X-Ray crystal structure of [{N(CH2CH2PPh2)3}PtAsPh2]BPh4

F. Cecconi, C. A. Ghilardi, S. Midollini, S. Moneti, A. Orlandini and G. Scapacci, J. Chem. Soc., Chem. Commun., 1990, 1583 DOI: 10.1039/C39900001583

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