Tungsten alkenyldiazenido complexes, which are obtained by the deprotonation of diazoalkane complexes trans-[WF(NN![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CRR′)(dpe)2][BF4](dpe = Ph2PCH2CH2PPh2) with lithium diisopropylamide (LDA) or NaN(SiMe3)2, undergo regioselective alkylation to give the C-alkylated diazoalkane complexes.
Y. Ishii, H. Miyagi and M. Hidai, J. Chem. Soc., Chem. Commun., 1990, 1569 DOI: 10.1039/C39900001569
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