Issue 21, 1990

µ-Peroxo-µ-oxo-bis[bis(trimethylsilylmethyl)tin]: the first structurally characterised main-group metal η2-peroxide, a formal tin analogue of an ozonide

Abstract

The title compound is the first µ-η2-peroxodimetallic species to be characterised for a main group metal, possessing a long peroxo O–O bond, and large C–Sn–C angles, and is an unexpected product from the oxidation of [SnR2][R = CH(SiMe3)2], with a structure analogous to an organic ozonide.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1461-1462

µ-Peroxo-µ-oxo-bis[bis(trimethylsilylmethyl)tin]: the first structurally characterised main-group metal η2-peroxide, a formal tin analogue of an ozonide

C. J. Cardin, D. J. Cardin, M. M. Devereux and M. A. Convery, J. Chem. Soc., Chem. Commun., 1990, 1461 DOI: 10.1039/C39900001461

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