Issue 20, 1990

Enzyme-catalysed baeyer–villiger oxidations of some substituted bicyclo[3.2.0]heptanones

Abstract

The ketones 1 and 4 are oxidized to γ-lactones 2 and 5 with low enantioselectivity by both Acinetobacter sp. NCIB 9871 and Pseudomonas sp. NCIB 9872; in contrast the ketones 7 and 10 are biotransformed to products 8/9 and 11 respectively of very high optical purity.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1438-1439

Enzyme-catalysed baeyer–villiger oxidations of some substituted bicyclo[3.2.0]heptanones

A. J. Carnell, S. M. Roberts, V. Sik and A. J. Willetts, J. Chem. Soc., Chem. Commun., 1990, 1438 DOI: 10.1039/C39900001438

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