Dichloromethane facilitates clean high-yield double addition of carbanions to [(η6-arene)2Fe]2+ dications affording bis(η5-cyclohexadienyl)iron or ‘pseudoferrocene’ compounds in accord with the Davies, Green, and Mingos rules; the crystal structure of one example has been determined.
K. C. Sturge and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1990, 1244 DOI: 10.1039/C39900001244
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