A highly stereoselective total synthesis of (–)-detoxinine (2) is achieved via diastereoselective epoxidation of allylic alcohol (9) and bromolactonization of syn-β-hydroxy-γ-amino acid (12).
H. Kogen, H. Kadokawa and M. Kurabayashi, J. Chem. Soc., Chem. Commun., 1990, 1240 DOI: 10.1039/C39900001240
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