Issue 17, 1990

Evidence for the technetium(VI) aquanitrido cation [{TcN(OH2)3}2(µ-O)2]2+ in solution: preparation and structure of [{TcN(S2CNEt2)}2(µ-O)2]

Abstract

Electrophoretic and spectroscopic data together with the isolation and structural characterisation of [{TcN(S2CNEt2)}2(µ-O)2] provide evidence for the formation of the TcVI aquanitrido dimer [{TcN(OH2)3}2(µ-O)2]2+ in solutions of weakly co-ordinating acids.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1163-1165

Evidence for the technetium(VI) aquanitrido cation [{TcN(OH2)3}2(µ-O)2]2+ in solution: preparation and structure of [{TcN(S2CNEt2)}2(µ-O)2]

J. Baldas, J. F. Boas, J. Bonnyman, S. F. Colmanet and G. A. Williams, J. Chem. Soc., Chem. Commun., 1990, 1163 DOI: 10.1039/C39900001163

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