Reactions of hexamesitylcyclotrigermane (1a) and tetrakis(2,6-diethylphenyl)digermene (3b) with tellurium at 80 °C produce telluradigermiranes (2a) and (2b) respectively; the structure of (2b) has been confirmed by a single-crystal X-ray diffraction study, showing the existence of a Ge2Te ring.
T. Tsumuraya, Y. Kabe and W. Ando, J. Chem. Soc., Chem. Commun., 1990, 1159 DOI: 10.1039/C39900001159
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