Jump to main content
Jump to site search

Issue 16, 1990
Previous Article Next Article

Nucleophilic addition to vinylketene- and vinylketenimine (allenylideneamine)tricarbonyliron(0) complexes

Abstract

Nucleophiles add to C-1 of (vinylketene)tricarbonyliron(0) complexes to give β,γ-unsaturated carbonyl derivatives, whereas nucleophilic attack on a (vinylketenimine)tricarbonyliron(0) analogue occurs at C-2 and leads, after an oxidative work-up, to β,γ-unsaturated amides containing an a quaternary centre.

Back to tab navigation

Article type: Paper
DOI: 10.1039/C39900001085
Citation: J. Chem. Soc., Chem. Commun., 1990,0, 1085-1086
  •   Request permissions

    Nucleophilic addition to vinylketene- and vinylketenimine (allenylideneamine)tricarbonyliron(0) complexes

    L. Hill, C. J. Richards and S. E. Thomas, J. Chem. Soc., Chem. Commun., 1990, 0, 1085
    DOI: 10.1039/C39900001085

Search articles by author

Spotlight

Advertisements