Issue 15, 1990

Synthesis, X-ray structure, and chemical properties of [Cu8(dmpz)8(OH)8](Hdmpz = 3,5-dimethylpyrazole). First example of a copper complex containing a planar ring of eight metal atoms

Abstract

Reaction of the polymeric copper(I)-3,5-dimethylpyrazolate, [Cu(dmpz)]n, with molecular dioxygen gives the octameric copper(II) complex, [Cu8(dmpz)8(OH)8], whose spectroscopic and chemical properties, and X-ray structure analysis are reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1021-1023

Synthesis, X-ray structure, and chemical properties of [Cu8(dmpz)8(OH)8](Hdmpz = 3,5-dimethylpyrazole). First example of a copper complex containing a planar ring of eight metal atoms

G. A. Ardizzoia, M. A. Angaroni, G. La Monica, F. Cariati, M. Moret and N. Masciocchi, J. Chem. Soc., Chem. Commun., 1990, 1021 DOI: 10.1039/C39900001021

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