The regiochemistry of anionic addition to phospha-ethyne is shown, using MO calculations, to be dependent on the nature of the nucleophile, the hydride ion leading to initial C-attack whereas the fluoride ion prefers P-addition; the latter is predicted to be stereospecific irrespective of the nucleophilic agent.
M. T. Nguyen, J. Chem. Soc., Chem. Commun., 1990, 989 DOI: 10.1039/C39900000989
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...