Issue 14, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation and characterization of [V3Cl5(tmeda)3][V(NPh2)4](tmeda =N,N,N′,N′-tetramethylethylenediamine): a VII–VIII mixed valence complex

Jilles J. H. Edema,   Auke Meetsma  and  Sandro Gambarotta  

Abstract

Reaction of trans-[VCl2(tmeda)2](tmeda =N,N,N′,N′-tetramethylethylenediamine) with an excess of NaNPh2 led to the formation of the VII–VIII mixed-valence species [V3Cl5(tmeda)3][V(NPh2)4], through an unusual disproportionation reaction.

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Article information

DOI
https://doi.org/10.1039/C39900000951
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 951-953

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Preparation and characterization of [V3Cl5(tmeda)3][V(NPh2)4](tmeda =N,N,N′,N′-tetramethylethylenediamine): a VII–VIII mixed valence complex

J. J. H. Edema, A. Meetsma and S. Gambarotta, J. Chem. Soc., Chem. Commun., 1990, 951 DOI: 10.1039/C39900000951

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