Rh(terpy)23+ and Rh(bpy)33+(terpy = 2,2′; 6′,2″-terpyridine; bpy = 2,2′-bipyridine) catalyse the regiospecific photochemical reduction of NAD+ into 1,4-NADH; Rh(terpy)23+ retains its catalytic activity in the photochemical reaction for longer than Rh(bpy)33+.
K. Umeda, A. Nakamura and F. Toda, J. Chem. Soc., Chem. Commun., 1990, 885 DOI: 10.1039/C39900000885
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