(R)-(–)-Muscone was prepared in 89% enantiomeric excess using newly devised chiral ligands such as (1R,2R,3S,4S)-3-[(1-methylpyrrolyl)methylamino]-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol in conjugate addition of methyl cuprate to (E)-2-cyclopentadecen-1-one.
K. Tanaka, H. Ushio and H. Suzuki, J. Chem. Soc., Chem. Commun., 1990, 795 DOI: 10.1039/C39900000795
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