The doubly-bridged iron porphyries (1) and (8) have been synthesized carrying a covalently bound, proximal S–Me ligand and an imidazole co-ordinating to the iron; UV and 1H NMR spectroscopy and electrochemistry show that compounds are close analogues of cytochrome c.
S. Matile and W. Woggon, J. Chem. Soc., Chem. Commun., 1990, 774 DOI: 10.1039/C39900000774
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