The gas-phase reaction of F– with several acetic acid derivatives (MeCOX) is shown to proceed primarily by proton abstraction in the collision complex, rather than nucleophilic displacement, leading to the facile formation of FHX– or CH2CFO–.
J. M. Riveros, J. Chem. Soc., Chem. Commun., 1990, 773 DOI: 10.1039/C39900000773
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