The frequency of the Raman-active Co–C bond stretch in photolabile methylcoenzyme B12 has been conclusively determined by the new technique of near-IR Fourier transform (FT) Raman spectroscopy to be 500 cm–1 for methylcobalamin and 470 Cm–1 for deuteriated methyl (CD3–) cobalamin.
S. Nie, P. A. Marzilli, L. G. Marzilli and N. Yu, J. Chem. Soc., Chem. Commun., 1990, 770 DOI: 10.1039/C39900000770
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