Alkylation of N-alkyl dihydronaphthalene-1-sulphonamides, derived by reduction with Li/liq. NH3, can be directed in certain cases to the naphthalene 3-position, depending mainly on the steric bulk of the N-alkyl group(s).
H. J. E. Loewenthal, J. Chem. Soc., Chem. Commun., 1990, 768 DOI: 10.1039/C39900000768
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