The complexation of natural polyphenols with malvin chloride has been examined; a model for the preferred mode of chelation of β-1,2,3,4,6-penta-O-galloyl-D-glucose (4) with various aromatic substrates (the ffavylium ion, caffeine, methylene blue, and daunomycin) is proposed.
Y. Cai, T. H. Lilley and E. Haslam, J. Chem. Soc., Chem. Commun., 1990, 380 DOI: 10.1039/C39900000380
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