The cluster benzene complex [Ru3(CO)9(µ3-η2:η2:η2-C6H6)] which contains a benzene ligand in a face-capping co-ordination mode has been prepared, and its molecular structure investigated by a single crystal X-ray analysis which provides unambiguous evidence for C–C length alternation.
B. F. J. Johnson, J. Lewis, M. Martinelli, A. H. Wright, D. Braga and F. Grepioni, J. Chem. Soc., Chem. Commun., 1990, 364 DOI: 10.1039/C39900000364
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