The reaction of Ni(cod)2(cod = cyclo-octadiene) with Sn(NBut)2SiMe2 has yielded Ni[Sn(NBut)2SiMe2]4, the first binary stannylene complex of the first transition series.
M. Veith, L. Stahl and V. Huch, J. Chem. Soc., Chem. Commun., 1990, 359 DOI: 10.1039/C39900000359
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