Issue 4, 1990

The structure of halogenometallate complexes dissolved in both basic and acidic room-temperature halogenoaluminate(III) ionic liquids, as determined by EXAFS

Abstract

The salts [MeEtim]2[MCl4]([MeEtim]+= 1-methyl-3-ethylimidazolium; M = Mn, Co, or Ni) are shown by EXAFS to dissolve in basic [MeEtim]Cl–AlCl3 ionic liquids to yield four-co-ordinate [MCl4]2–, and to dissolve in acidic [MeEtim]Cl–AlCl3 ionic liquids to yield six-co-ordinate [M(AlCl4)3] anions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 315-316

The structure of halogenometallate complexes dissolved in both basic and acidic room-temperature halogenoaluminate(III) ionic liquids, as determined by EXAFS

A. J. Dent, K. R. Seddon and T. Welton, J. Chem. Soc., Chem. Commun., 1990, 315 DOI: 10.1039/C39900000315

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