Buff's ‘ferrocyanäthyl’ consists of hexakis(hydrogen isocyanide)iron2+ chloride, the cation of which is stabilized through strong hydrogen bonding {d[(FeC)N ⋯ O(H)Et] 2.509(3)Å} to a second co-ordination sphere of six molecules of ethanol.
D. Rieger, F. E. Hahn and W. P. Fehlhammer, J. Chem. Soc., Chem. Commun., 1990, 285 DOI: 10.1039/C39900000285
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