Issue 2, 1990

[2 + 2] Cycloadditions between electron-poor phospha-alkene complexes and electron-rich alkenes or alkynes, a new route to phosphetane and 1,2-dihydrophosphete rings

Abstract

Ethoxycarbonyl-C-substituted phospha-alkene P-W(CO)5 complexes instantly react at low temperature with enamines, enol ethers, ynamines, and ethoxyacetylene to yield the corresponding phosphetane and 1,2-dihydrophosphete [2 + 2] cycloadducts.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 153-154

[2 + 2] Cycloadditions between electron-poor phospha-alkene complexes and electron-rich alkenes or alkynes, a new route to phosphetane and 1,2-dihydrophosphete rings

A. Marinetti and F. Mathey, J. Chem. Soc., Chem. Commun., 1990, 153 DOI: 10.1039/C39900000153

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