Issue 1, 1990

The chemistry of C6S10: a channel structure for C6S10(CS2)0.5 and access to the versatile DMAD·C3S4O (DMAD = dimethylacetylenedicarboxylate)

Abstract

Treatment of (Et4N)2[Zn(C3S5)2] with SO2Cl2 gives molecular C6S10(1), structurally characterized as (1)·(CS2)0.5, which has a channel structure; a two step conversion affords bicyclic tetrathiaindenone OC3S4·C2(CO2Me)2 which is used to make new alkenedithiolate derivatives.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 34-36

The chemistry of C6S10: a channel structure for C6S10(CS2)0.5 and access to the versatile DMAD·C3S4O (DMAD = dimethylacetylenedicarboxylate)

X. Yang, T. B. Rauchfuss and S. Wilson, J. Chem. Soc., Chem. Commun., 1990, 34 DOI: 10.1039/C39900000034

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