Issue 18, 1990

Two-photon photoselection: an irreducible tensor analysis

Abstract

A detailed symmetry analysis of two-photon photoselection is presented. The adoption of irreducible tensor methods facilitates the characterization of two-photon excited states probed either by fluorescence or by the absorption of a third photon from a probe laser beam. The theory also enables information on any intervening rotational motion to be derived from suitable polarization studies. A new generalized scheme for the symmetry classification of multiphoton transitions is applied to the photoselection process.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans., 1990,86, 3051-3066

Two-photon photoselection: an irreducible tensor analysis

D. L. Andrews and B. S. Webb, J. Chem. Soc., Faraday Trans., 1990, 86, 3051 DOI: 10.1039/FT9908603051

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