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Issue 3, 1990
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Spectroscopic studies on the hexafluorides of ruthenium and rhodium isolated in low-temperature matrices

Abstract

New syntheses of RuF6 and RhF6 are reported involving fluorination of the corresponding pentafluorides at 220 °C and 30 atm. Infra-red spectra for RuF6 and RhF6 isolated in nitrogen and argon matrices at 12 K have been recorded and assigned. The u.v.–visible spectra in nitrogen matrices are complex containing both fluorine-to-metal charge-transfer and dd transitions. Assignments for the main features are proposed.

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J. Chem. Soc., Dalton Trans., 1990, 715-718
Article type
Paper

Spectroscopic studies on the hexafluorides of ruthenium and rhodium isolated in low-temperature matrices

A. K. Brisdon, P. J. Jones, W. Levason, J. S. Ogden, J. H. Holloway, E. G. Hope and G. Stanger, J. Chem. Soc., Dalton Trans., 1990, 715
DOI: 10.1039/DT9900000715

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