Calculated energy profiles for the opening of six methyl bromonium ions show single, shallow or very flat minima corresponding to symmetrical or highly asymmetrical bridged structures depending on the symmetry of the substitution but not on the number of methyl groups.
B. Galland, E. M. Evleth and M. Ruasse, J. Chem. Soc., Chem. Commun., 1990, 898 DOI: 10.1039/C39900000898
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