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Issue 14, 1990
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Preparation of organosilicon derivatives of cobalt-complexed but-2-yne-1,4-diol. X-Ray crystal structure of [Co2(CO)5(PPh3){µ-C2(CH2)2O2(SiPh2)2O2(CH2)2C2}Co2(CO)2(PPh3)]

Abstract

Reactions of [Co2(µ-HOCH2C2CH2OH)(CO)6] with diorganodichlorosilanes in the presence of triethylamine afford hexacarbonyldicobalt-complexed 1,3-dioxa-2-silacycloalkynes.

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Article information


J. Chem. Soc., Chem. Commun., 1990, 993-994
Article type
Paper

Preparation of organosilicon derivatives of cobalt-complexed but-2-yne-1,4-diol. X-Ray crystal structure of [Co2(CO)5(PPh3){µ-C2(CH2)2O2(SiPh2)2O2(CH2)2C2}Co2(CO)2(PPh3)]

R. H. Cragg, J. C. Jeffery and M. J. Went, J. Chem. Soc., Chem. Commun., 1990, 993
DOI: 10.1039/C39900000993

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