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Issue 3, 1990
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The photochemistry of nitrosobenzene: direct observation of the phenyl radical–nitric oxide triplet radical pair in argon at 12 K

Abstract

Photolysis of nitrosobenzene monomer in an argon matrix at 12 K efficiently yields the phenyl radical and nitric oxide as a triplet radical pair, which are characterized by IR, UV, and ESR spectroscopy; these species recombine upon warming to 25–40 K to regenerate nitrosobenzene.

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Article information


J. Chem. Soc., Chem. Commun., 1990, 227-229
Article type
Paper

The photochemistry of nitrosobenzene: direct observation of the phenyl radical–nitric oxide triplet radical pair in argon at 12 K

W. G. Hatton, N. P. Hacker and P. H. Kasai, J. Chem. Soc., Chem. Commun., 1990, 227
DOI: 10.1039/C39900000227

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