The pinacol rearrangement in the solid state was found to proceed faster and more selectively than that in solution. A highly selective rearrangement was observed in the reaction of pinacol in its hostguest complex in the solid state.
F. Toda and T. Shigemasa, J. Chem. Soc., Perkin Trans. 1, 1989, 209 DOI: 10.1039/P19890000209
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