Trimethyltin hydride reacts with SiF3SiF3 or SiF3SiF2H to give the new compound SnMe3(SiF3) in 75–80% yield. No reaction was observed between SnMe3H and SiF3SiH3. Hydrogen–deuterium exchange was observed between tin and silicon during the course of deuterium-labelling experiments. Dimethylstannylene (SnMe2) was implicated as an intermediate by trapping experiments in the thermolysis of SnMe3(SiF3).
J. J. D'Errico and K. G. Sharp, J. Chem. Soc., Dalton Trans., 1989, 1879 DOI: 10.1039/DT9890001879
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