The hydrindanol (2), a C/D-ring synthon of vitamin D3 metabolites, has been synthesized enantioselectively by the use of stereoselective epoxy alcohol-initiated polyalkene cyclisation as a key step.
S. Hatakeyama, H. Numata, K. Osanai and S. Takano, J. Chem. Soc., Chem. Commun., 1989, 1893 DOI: 10.1039/C39890001893
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