Issue 21, 1989

Synthesis and X-ray structure of bis(trifluoromethyl)(N,N-diethyldithiocarbamato)-copper; a remarkably stable perfluoroalkylcopper(III) complex

Abstract

The reaction between trifluoromethylcadmium reagent and Br2Cu(edtc)(edtc =N,N-diethyldithiocarbamato) or CdI+[(CF3)2Cu] with [Et2NC(S)S]2 in DMF (dimethylformamide) at –30°C yields the stable CuIII perfluoroalkylcopper complex, (CF3)2CuSC(S)NEt2.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1633-1634

Synthesis and X-ray structure of bis(trifluoromethyl)(N,N-diethyldithiocarbamato)-copper; a remarkably stable perfluoroalkylcopper(III) complex

M. A. Willert-Porada, D. J. Burton and N. C. Baenziger, J. Chem. Soc., Chem. Commun., 1989, 1633 DOI: 10.1039/C39890001633

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